ADVANCED NANO AND ORGANIC SYNTHESIS (NTM 812)
Organic
Synthesis: Oxidation and reduction methods, stereochemistry and products from
hydride and dissolving-metal reductions. Synthetic organic applications of
phosphorus, silicon, titanium, copper, palladium and ruthenium. Chemistry of
heterocycles. Mechanisms of molecular rearrangements involving carbo-cations,
electron deficient nitrogen and oxygen species, and of carbonyl compounds.
Experimental and instrumental methods and techniques of organic chemistry. Nano
Synthesis methods: Electrosynthesis, chemical, thermal and microwave synthesis.
Thin Film Deposition Methods. Thermal chemical vapor deposition (CVD),
catalytic synthesis and plasma synthesis. Tuning nanoparticles sizes, shapes and dimensionality by appropriate choice of the chemical
precursors and/or of the reaction’s conditions. Properties of nanomaterials: Chemical,
electrochemical, spectroscopic, microscopic, mechanical, electrical and optical
properties of materials. Synthetic nanomaterials: Ceramics, glasses, polymers,
fullerenes, nanotubes, graphenes, carbon nanotubes, metal oxides and catalysts
(PGMs etc), nanocrystals, nanocomposites, nano-alloys, quantum dots, zeolites,
metal-organic frameworks.